Identify Hazardous Chemicals

 The first step in managing risk involves the identification of all chemicals that are likely to be used, handled, stored or generated at the workplace. A person conducting business or undertaking must obtain and provide access to Safety Data Sheets. A current SDS must be readily accessible to workers involved in using, handling and storing the hazardous chemical at the workplace and emergency service workers or anyone who is likely to be exposed to the hazardous chemical. 



Access to SDS in the workplace

The SDS must be kept in a location near the work area where the substance is used; either as a hard copy, soft copy or any other format (such as an online version )and workers likely to be exposed to the hazardous chemical must know how to find the SDS. 


Obligations relating to SDS in the workplace

Safety Data Sheets and other matters include manufactures and importers to ensure that hazardous chemicals are correctly labelled as soon as practicable after manufacturing or importing the hazardous chemicals. 

 

Other sources of information regarding hazards and risks associated with the use, handling, generation and storage of hazardous chemicals can be obtained from the following sources:

 

Category

Information Source

Employment and training

Training courses, trade unions and employer associations

Health and Safety

Work health and safety consultants, employers or industry associations, WHS representatives

Authoritative

Internet searches of authoritative websites, e.g. Safework Australia, WHS Regulators, AICIS, SUSMP, TGA, NTC, OSHA, EC Joint Research Centre, etc.

Incident records

Information sheet used for recording a work-related death, injury, illness or dangerous incident


In Australia, hazardous chemicals are defined according to the WHS Regulations: A hazardous chemical means any substance, mixture or article that satisfies the criteria for a hazard class in the GHS. 


Chemicals may present immediate or long-term injury or illness to people caused by their health and physicochemical hazards. Chemicals can present:

 

  • Physical hazard
  • Health hazard
  • Environmental hazard

 



So What is a Safety Data Sheet?


A Safety Data Sheet (SDS) is a document prepared by the manufacturer or importer of a hazardous chemical to provide detailed information regarding the hazardous product as per compliance requirements.   The manufacturer or importer of the hazardous chemical must provide the current (up to date) SDS for the hazardous chemical to any person, if the person is likely to be affected by the hazardous chemical or to any person who asks for it. When a hazardous chemical is first supplied to a workplace, the SDS must be provided with the hazardous chemical. An SDS is used for cataloguing information on chemicals, chemical compounds and chemical mixtures and provides information on the hazards associated with a material and instructions on how to work with the material in a way that is safe. It also includes information such as:

 

  • Physical data (e.g. boiling point, melting point, flash point, vapour pressure, etc)
  • Physical state (powder, liquid, gas, pellet, etc)
  • First aid
  • Health effects
  • Reactivity
  • Recommendations for storage and disposal
  • Toxicity
  • Personal Protective Equipment (PPE)
  • Spill handling procedures in case of emergency.


This information above is split into 16 clearly defined sections, with the information for each section. Hazards can be identified from Section 2 of an SDS; where a legislative statement will be provided to identify the classification, system used for the classification of the material/substance/product. The following table provides a summary of each section of an SDS, however, this is not a full comprehensive list of information required on the SDS, manufacturers/importers can reference the full detailed data fro the Code of Practice for Creating an SDS.


Section

Headers

1. Product identifier & identity for the chemical

  • Product Identifier
  • Other means of identification
  • Recommended use of the chemical and restrictions on use
  • Suppliers name, address and phone number
  • Emergency phone number

2. Hazard Identification

  • Classification of the hazardous chemical
  • Label elements, including precautionary statements
  • Other hazards which do not result in classification

3. Composition/information on ingredients

  • Identity of chemical ingredients
  • CAS number and other unique identifiers
  • Concentration of ingredients

4. First Aid Measures

  • Description of necessary first aid measures
  • Symptoms caused by exposure
  • Medical Attention and Special Treatment

5. Fire Fighting Measures

  • Suitable extinguishing media
  • Specific hazards arising from the chemical
  • Special protective equipment and precautions for fire fighters

6. Accidental release measures

  • Personal precautions, protective equipment and emergency procedures
  • Environmental precautions
  • Methods and materials for containment and cleaning up

7. Handling and Storage

  • Precautions for safe handling
  • Conditions for safe storage, including any incompatibilities

8. Exposure controls/personal protection

  • Control parameters – exposure standards, biological monitoring
  • Appropriate engineering controls
  • Personal protective equipment (PPE)

9. Physical and chemical properties

  • Appearance
  • Odour
  • Odour threshold
  • pH
  • Melting point/freezing point
  • Boiling point and boiling range
  • Flash point
  • Evaporation rate
  • Flammability
  • Upper/lower flammability or explosive limits
  • Vapour pressure
  • Vapour density
  • Relative density
  • Solubility
  • Partition coefficient: n-octanol/water
  • Auto-ignition temperature
  • Decomposition temperature
  • Viscosity
  • Specific heat value
  • Particle size
  • Volatile organic compounds content
  • % volatile
  • Saturated vapour concentration
  • Release of invisible flammable vapours and gases

Additional parameters

  • Shape and aspect ratio
  • Crystallinity
  • Dustiness
  • Surface area
  • Degree of aggregation or agglomeration
  • Ionisation (redox potential) 
  • Biodurability or biopersistence

10. Stability and Reactivity

  • Reactivity
  • Chemical stability
  • Conditions to avoid
  • Incompatible materials and possible hazardous reactions
  • Hazardous decomposition products

11. Toxicological information

  • Information on routes of exposure
  • Symptoms related to exposure
  • Numerical measures of toxicity
  • Immediate, delayed and chronic health effects from exposure
  • Exposure Levels
  • Interactive effects
  • Data limitations

12. Ecological information

  • Ecotoxicity
  • Persistence and degradability
  • Bioaccumulative potential
  • Mobility in soil
  • Other adverse effects

13. Disposal considerations

  • Safe handling and disposal methods
  • Disposal of any contaminated packaging
  • Environmental regulations

14. Transport information

  • UN number
  • Proper shipping name
  • Transport hazard class(es)
  • Packing group
  • Environmental hazards
  • Special precautions during transport
  • Hazchem Code

15. Regulatory information

  • Safety, health and environmental regulations specific for the product in question
  • Poisons Schedule number

16. Other information

  • Date of preparation or review
  • Key abbreviations or acronyms used

  


Below are some of the basic requirements for industry practice. 


  • Review required every 5 years
  • Amended if new information about hazardous chemical is known
  • Review not necessary if manufacturer or importer has not produced chemical in last 5 years
  • SDS should be made available after hazardous chemical is withdrawn from sale
  • SDS translations are acceptable and attached to original SDS

For further details, click here do download the code of practice for the preparation of SDS.